Hydroformylation in fluorous solvents.
نویسندگان
چکیده
Triaryl-phosphines and -phosphites bearing fluorous ponytails give high rates, good linear selectivity and good retention of catalyst in the fluorous phase during hydroformylation of alkenes in fluorous solvents.
منابع مشابه
Fluorous methods for synthesis and separation of organic molecules*
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The fluorous biphase system has been applied successfully to a wide range of homogeneous catalyses with excellent catalyst recovery and reuse being reported. However, it is unlikely to be exploited commercially because of intersolvent leaching problems, the prohibitive expense of the perfluorocarbon solvents and concerns about their environmental persistence. An alternative approach, designed b...
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ورودعنوان ژورنال:
- Chemical communications
دوره 7 شماره
صفحات -
تاریخ انتشار 2002